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What are the main uses of 3- (N, N-dimethylcarbamoxy) pyridine?
3 - (N, N -dimethylhydroxylaminoethoxyacetamide) The main use of this substance is in space propellant treatment and related operations in the nuclear industry.
In the field of space propellant treatment, it can be used as a propellant stabilizer. Space propellants contain many highly active chemical substances, and stability is essential. This substance can interact with the active components in the propellant, inhibiting the spontaneous decomposition reaction of the propellant through a special chemical mechanism, thereby ensuring that the propellant remains stable during storage and use. For example, during long-term storage, it can effectively delay the deterioration of the propellant and reduce the risk of space mission failure due to changes in propellant properties.
In the nuclear industry, it plays a key role in the nuclear fuel reprocessing process. After the spent fuel is dissolved, the solution contains a variety of radionuclides and impurities. 3- (N, N-dimethylhydroxylaminoethoxyacetamide) can selectively complex with specific metal ions, thereby realizing the separation and purification of these ions. For example, in the extraction and purification of important nuclides such as uranium and plutonium, with its unique coordination ability, the target nuclide can be efficiently separated from the complex mixed system, and it has good radiation stability. It is not easy to decompose in a radioactive environment, and can stably exert its separation function to ensure the smooth development of nuclear fuel reprocessing.
What are the physical properties of 3- (N, N-dimethylcarbamoxy) pyridine?
3 - (N, N -dimethylaminoethoxyethoxy methyl etheroxy) This substance has a wide range of physical properties.
Looking at its morphology, under normal temperature and pressure, it is often colorless to light yellow transparent liquid, uniform in texture and good fluidity, like a smart stream, without precipitation or suspended matter.
Smell its smell, with a slight special smell, not pungent and intolerable, but also has a unique recognition, like a subtle background hidden behind fragrance.
Measuring its density, it is within a specific range. Compared with common organic solvents, its specific gravity is unique, just like finding a unique balance on the balance of density. The boiling point and melting point are also fixed, and the boiling point is in the corresponding temperature range. At this temperature, the substance seems to break free and sublimate from the liquid state to the gaseous state; the melting point is near a certain temperature. At this temperature, the substance melts from the solid state to the liquid state, completing the ingenious transformation of the form.
When it comes to solubility, it shows good solubility in many organic solvents, and can be miscible with alcohols, ethers and other organic solvents in different proportions, just like the water droplets that blend into Wang Yang, blending harmoniously; in water, although not completely miscible, it also has a certain solubility, just like finding a limited shelter in the world of water. < Br >
In addition, its flash point is at a certain value, which is a key indicator for measuring its fire risk, revealing its reaction characteristics to fire sources under specific conditions, just like setting an invisible limit for its flammability.
The physical properties of this substance may vary slightly due to changes in environmental conditions, but under normal circumstances, it is generally maintained within the above range.
What are the chemical properties of 3- (N, N-dimethylcarbamoxy) pyridine
3 - (N, N -dimethylaminoethoxyethoxyacetonitrile) is an organic compound with unique chemical properties and has the following terminals:
1. ** Nucleophilic Substitution Reactivity **: The intramolecular ethoxy group is connected to the acetonitrile group, and the cyanyl group in the acetonitrile group has a certain nucleophilicity. Under suitable conditions, the cyanyl group can participate in nucleophilic substitution reactions, such as reacting with halogenated hydrocarbons. The carbon atoms in the cyanyl group will attack the carbon atoms attached to the halogenated atoms in the halogenated hydrocarbons, and the halogenated atoms will leave to form new cyanide-containing compounds. This is an important reaction path for growing carbon chains and building complex organic molecular structures.
2. ** Basic characteristics **: N, N - dimethylamino partially contains nitrogen atoms. There are lone pairs of electrons on the nitrogen atom, making it alkaline. It can react with acids to form salt compounds. For example, when reacted with hydrochloric acid, nitrogen atoms will bind protons to generate corresponding ammonium salts. This basic characteristic can be used in organic synthesis to regulate the pH of the reaction system, or to participate in specific reactions as a catalyst.
3. ** Tendency for hydrolysis **: Acetonitrile groups can be hydrolyzed under acid or base catalysis conditions. Under acidic conditions, cyanyl groups are gradually hydrolyzed to form amides, which continue to hydrolyze to form carboxylic acids and ammonia; under basic conditions, cyanyl groups are hydrolyzed to form carboxylate and ammonia. If heated in an aqueous solution of sodium hydroxide, a hydrolysis reaction will occur to generate corresponding carboxylic salts and ammonia. This reaction can be used in organic synthesis to prepare compounds containing carboxyl groups.
4. ** Complexation with metal ions is possible **: The nitrogen atom in the molecule can be used as a ligand, and it complexes with some metal ions by virtue of its lone pair electrons. For example, it forms complexes with transition metal ions, which has potential application value in the field of catalysis. The formed complexes may act as catalysts to catalyze certain organic reactions and improve the reaction rate and selectivity.
What are the synthesis methods of 3- (N, N-dimethylcarbamoxy) pyridine?
To prepare 3 - (N, N - dimethylaminoethoxyethoxy) propionitrile, there are many ways to synthesize it, and this is the way for you.
First, 3-chloropropionitrile and N, N - dimethylaminoethoxyethanol are used as raw materials to react under basic conditions. This reaction uses a base as a catalyst to promote nucleophilic substitution of the two. Bases, such as potassium carbonate, sodium carbonate, etc., can enhance the nucleophilicity of oxygen atoms in N, N - dimethylaminoethoxyethanol, making it easy to attack the carbon atoms connected to chlorine in 3 - chloropropionitrile, and the chlorine atoms leave and become the target product. When reacting, it is necessary to pay attention to the control of the reaction temperature and time. If the temperature is too high, it may cause a cluster of side reactions; if the time is too short, the reaction will not be complete.
Second, first react with 3-hydroxypropionitrile and halogenated ethoxyethane to obtain 3- (ethoxyethoxy) propionitrile, and then react with dimethylamine. In the first step, 3-hydroxypropionitrile and halogenated ethoxyethane undergo etherification reaction under the action of a suitable catalyst. The catalysts used can be sulfuric acid, p-toluenesulfonic acid, etc. The key to this step is to control the reaction conditions so that the etherification reaction can proceed smoothly. Then, the resulting product reacts with dimethylamine, and the amine group replaces the hydroxyl group to form 3- (N, N-dimethylaminoethoxyethoxy) propionitrile. This reaction may require heating and pressure to promote the reaction speed.
Third, starting from ethylene oxide, first react with 3-chloropropionitrile to form an intermediate, and then react with dimethylamine. Ethylene oxide and 3-chloropropionitrile are ring-opening and added under the action of a catalyst to form a chlorine-containing intermediate. This catalyst can be selected from Lewis acids. After that, the intermediate reacts with dimethylamine, the nitrogen atom of dimethylamine attacks the chlorine-containing carbon atom, and the chlorine atom leaves to obtain the target product. This route requires attention to the safe operation of ethylene oxide, as it is flammable and explosive.
The above synthesis methods have their own advantages and disadvantages. When applying in practice, the choice should be made carefully according to factors such as the availability of raw materials, cost considerations, and difficulty of reaction conditions.
What are the precautions for using 3- (N, N-dimethylcarbamoxy) pyridine?
3 - (N, N -Dimethylaminoethoxyethoxyacetonitrile) During the use of this product, the following things should be paid attention to:
First, safety protection is essential. Because it has certain chemical activity, be sure to wear suitable protective equipment, such as gloves, goggles and protective clothing, when contacting it, to prevent the substance from touching the skin and eyes and causing unnecessary damage. If you contact it inadvertently, rinse it with plenty of water immediately, and seek medical attention in a timely manner according to the specific situation.
Second, storage conditions should not be ignored. Store it in a cool, dry and well-ventilated place, away from fire and heat sources, and avoid direct sunlight. At the same time, it should be stored separately from oxidants, acids, alkalis and other substances to prevent dangerous chemical reactions.
Third, the use environment should be kept well ventilated. During operation, volatile substances may be generated. Good ventilation can reduce the concentration of the substance in the air and reduce the risk of inhalation. If used in a confined space, effective ventilation equipment or respiratory protection devices should be equipped.
Fourth, strictly follow the operating procedures. Before use, it is necessary to fully understand its chemical properties and reaction characteristics, and operate according to the established process. Do not change or simplify the steps without authorization. During use, carefully observe the reaction phenomenon. If there is any abnormality, the operation should be stopped immediately and corresponding measures should be taken.
Fifth, do a good job of waste disposal. After use, the remaining substances and related waste cannot be discarded at will. They must be properly disposed of in accordance with relevant laws and regulations to prevent pollution to the environment.