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What is the chemical structure of 2,2 '-disulfanediylbis (pyridine) 1,1' -dioxide?
The chemical substance corresponding to 2% 2C2% 27 - disulfanediylbis%28pyridine%29 + 1% 2C1% 27 - dioxide is 2,2 '-disulfide-1,1' -dioxide. The chemical structure of this substance is actually composed of two pyridine rings connected by disulfide bonds, and the nitrogen atom of the pyridine ring is oxidized to N-oxide form.
Looking at this structure, the pyridine ring is a nitrogen-containing six-membered aromatic heterocyclic ring with a stable conjugate system. The two pyridine rings are connected by disulfide bonds (-S-S -), which give the molecule a certain degree of flexibility, but also limit its rotational freedom. Furthermore, the nitrogen atom on the pyridine ring is oxidized to form N-oxide. This N-oxide functional group not only changes the electron cloud distribution of the pyridine ring, but also affects its aromaticity and chemical activity. Due to the high electronegativity of the oxygen atom, it can participate in non-covalent interactions such as hydrogen bonds, which has a great impact on the physical and chemical properties and biological activities of the molecule.
Overall, the chemical structure of 2,2 '-disulfide bis (pyridine) -1,1' -dioxide fuses the aromatic properties of the pyridine ring, the connection properties of the disulfide bond and the activity properties of the N-oxide, resulting in its unique chemical properties, which may have potential application value in materials science, medicinal chemistry and other fields.
What are the physical properties of 2,2 '-disulfanediylbis (pyridine) 1,1' -dioxide?
2% 2C2% 27 - disulfanediylbis%28pyridine%29 + 1% 2C1% 27 - dioxide is 2,2 '-disulfide bis (pyridine) 1,1' -dioxide, which has the following physical properties:
In terms of view, it is often powdery, white and fine in color, like snow in the world, delicate and clean. Under normal conditions, it is stable but not impatient, but in special circumstances, it is different.
The melting point is about 180 to 184 degrees Celsius, just like the change of phenology. At this time, the shape changes gradually, from solid to melt. Its solubility is insoluble in water, just like the opposite of oil and water, which is difficult to blend; however, in organic solvents, such as methanol, ethanol, and dichloromethane, it is soluble, as if a wanderer is returning home and finding a suitable place.
Smell it, no pungent odor, peaceful breath, no disturbing smell. Its density is moderate, and it has its own trade-off among similar substances. These physical properties are due to the structure of molecules and the arrangement of atoms, and various factors interact to achieve this characteristic.
In which fields is 2,2 '-disulfanediylbis (pyridine) 1,1' -dioxide used?
2% 2C2% 27 - disulfanediylbis%28pyridine%29 1% 2C1% 27 - dioxide, this is the name of the chemical substance, the Chinese name is or 2,2 '-disulfide (pyridine) -1,1' -dioxide. It has applications in many fields, and listen to me one by one.
In the field of medicine, this substance may have antibacterial and anti-inflammatory effects. Due to its unique chemical structure, it can inhibit the growth and reproduction of bacteria and fungi. Just as ancient healers used herbs to treat the evils of disease, this chemical has its molecular properties to fight against bacteria. For example, in some skin inflammation treatment attempts, medicines containing this ingredient may improve symptoms, like good medicines applied to the affected area to relieve discomfort.
In the field of materials science, 2,2 '-disulfide bis (pyridine) -1,1' -dioxide may be used as an additive. It can enhance the stability and durability of the material, just like putting a strong armor on the material. For example, in some polymer materials, after adding this substance, the anti-aging properties of the material can be improved and the service life can be extended, just like a strong fortress to resist the erosion of time.
Furthermore, in agriculture, it may also have its uses. It may serve as a pesticide auxiliary to enhance the effect of pesticides. Just like marching in ancient times to fight a war, having auxiliary power can enhance the combat effectiveness of the army. After adding this substance, the adhesion and permeability of pesticides can be improved, and they can act more effectively on diseases and insects and protect the growth of crops.
In addition, in the field of industrial catalysis, this substance may be used as a component of special catalysts. Catalysts are like the guides of chemical reactions, and as part of them, they can adjust the rate and selectivity of catalytic reactions. As if in the palace of chemical reactions, it guides the reaction in the right direction, making the reaction more efficient to reach the target product and promoting the process of industrial production.
What are the synthesis methods of 2,2 '-disulfanediylbis (pyridine) 1,1' -dioxide
To make 2,2 '-disulfide bis (pyridine) -1,1' -dioxide, there are various methods. First, you can start with pyridine and disulfide and go through the oxidation step. First, take an appropriate amount of pyridine, add an appropriate amount of disulfide in a specific container, and the two need to be prepared in a precise ratio. Afterwards, slowly add a suitable oxidant, such as hydrogen peroxide, and the dropwise addition speed must be slow and uniform. At the same time, the temperature and duration of the reaction also need to be carefully controlled. In this process, if the temperature is too high, the side reaction will be generated, if it is too low, the reaction will be delayed, if the time is not enough, if it is too long, it may cause the product to decompose.
Second, using sulfur-containing pyridine derivatives as raw materials can also be achieved through specific chemical reactions. Take this derivative, place it in a suitable reaction system, add the necessary reagents, and adjust the reaction conditions, such as pH, temperature, etc., to promote its specific transformation, and then generate the target product.
Third, you can also use the method of catalytic reaction. Choose the right catalyst and add the reaction mixture. The catalyst can change the rate and path of the chemical reaction, making the reaction easier to generate 2,2 '-disulfide bis (pyridine) -1,1' -dioxide. During the reaction process, all factors need to be closely monitored to obtain a pure and sufficient amount of product. Each method has its own advantages and disadvantages, and the choice needs to be weighed according to actual needs.
How stable is 2,2 '-disulfanediylbis (pyridine) 1,1' -dioxide?
2% 2C2% 27 - disulfanediylbis%28pyridine%29 1% 2C1% 27 - dioxide, this is the expression of chemical substances, usually translated as 2,2 '-disulfide bis (pyridine) 1,1' -dioxide. In terms of its stability, it is necessary to analyze the chemical structure in depth.
Looking at its structure, the pyridine ring has a certain conjugated system, which endows the molecule with specific stability. Among them, the sulfur atom is connected to the pyridine ring, and the valence state and bonding mode of sulfur have a great influence on the stability. The disulfide bond (-S-S-) can break under certain conditions, which is one of the key factors affecting its stability. When in an oxidizing environment, the disulfide bond may be further oxidized, resulting in structural changes.
From the perspective of spatial structure, two pyridine rings are connected by disulfide bonds, and the steric hindrance effect will also affect the stability. If the steric hindrance of surrounding groups is large, the molecular conformation is relatively stable; conversely, the molecular flexibility increases, and the stability may decrease.
External conditions have a significant impact on its stability. When the temperature increases, the molecular thermal motion intensifies, and the disulfide bond is more likely to break and the stability decreases. In an acid-base environment, the substance may react with acid and base. Under acidic conditions, the nitrogen atom of the pyridine ring is protonated, changing the molecular charge distribution and chemical properties; under basic conditions, the disulfide bond may also undergo reactions such as hydrolysis, resulting in structural changes and impaired stability.
Solvent properties are also critical. In polar solvents, the interaction between molecules and solvents is strong, which may affect the stability of disulfide bonds; in non-polar solvents, the intermolecular forces are mainly van der Waals forces, which have different effects on stability.
In summary, the stability of 2,2 '-disulfide bis (pyridine) 1,1' -dioxide is restricted by its own structure such as disulfide bonds, pyridine ring conjugate system, spatial steric resistance, and external conditions such as temperature, acid and base, and solvents. Practical application and storage need to comprehensively consider these factors to ensure its stability.