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2,2 ': 6', 2 '-terpyridine, 4' - (4-bromophenyl) - What are the chemical properties of
2%2C2%27%3A6%27%2C2%27%27 - terpyridine% 2C 4% 27 - (4 - bromophenyl) - This compound is an organic compound with unique chemical properties. The pyridine rings are connected to each other in its structure, and the 4% 27 position is connected with bromophenyl groups.
From the perspective of physical properties, due to the large conjugated system, it may have a certain color and good thermal stability. In organic solvents, it may have a certain solubility, depending on the polarity of the solvent.
In terms of chemical properties, the nitrogen atom of the pyridine ring has lone pairs of electrons, which can be used as a ligand to coordinate with metal ions to form complexes. This property may have important applications in the fields of catalysis and materials science. The bromophenyl part contains bromine atoms with high activity, which can participate in a variety of organic reactions, such as nucleophilic substitution reactions, which can be replaced by other functional groups, expand molecular structures, and synthesize various derivatives.
Due to its conjugate structure, molecules may have photoelectric properties, and may have potential application value in optoelectronic devices, such as organic Light Emitting Diodes, solar cells, etc. However, the specific properties of this substance still need to be accurately determined experimentally, and many theoretical predictions have yet to be verified in practice.
2,2 ': 6', 2 '-terpyridine, 4' - (4-bromophenyl) - in which areas it is used
2%2C2%27%3A6%27%2C2%27%27 - terpyridine% 2C 4% 27 - (4 - bromophenyl) - This material is useful in various fields. It can be used as a primitive for the construction of novel functional materials in the field of materials science. With its unique structure, it can coordinate and complex with metal ions, and then prepare materials with special optical, electrical and magnetic properties. For example, in luminescent materials, the luminescent wavelength and efficiency of materials can be adjusted, making new developments in lighting, display and other fields.
In the field of chemical sensing, it can keenly identify specific substances. Due to its specific binding check point to certain ions or molecules, it can accurately detect the presence and concentration of targets through color changes, fluorescence signal changes, etc., and make great contributions to environmental monitoring and biomedical detection. For example, it can be used to detect the content of heavy metal ions in water, protect the environment and human health.
In the field of catalysis, complexes formed after coordination with metals often have high catalytic activity. It can reduce the activation energy of reactions, accelerate the process of various chemical reactions, and improve production efficiency, reduce costs, and promote the development of the chemical industry in industrial production processes such as organic synthesis.
In the field of biomedicine, it may be able to participate in the design of targeted drugs. With the interaction with specific biomolecules, precise drug delivery can be achieved, drug efficacy can be enhanced, damage to normal tissues can be reduced, and new paths can be opened up for disease treatment.
In summary, 2%2C2%27%3A6%27%2C2%27%27 - terpyridine% 2C 4% 27 - (4 - bromophenyl) - has important application value in materials, sensing, catalysis, biomedicine and many other fields, and promotes technological innovation and development in various fields.
What is the synthesis method of 2,2 ': 6', 2 '-terpyridine, 4' - (4-bromophenyl) -
To prepare 2,2 ': 6', 2 '-tripyridine-4' - (4-bromophenyl), the method is as follows:
First take the appropriate raw material, the raw material must be a pyridine-containing structure and have a modifiable check point, and a reagent containing 4-bromophenyl, both in a certain proportion of substances, such as 1:1.2 to 1:1.5 ratio, put into the reactor. An appropriate amount of organic solvent, such as dichloromethane, N, N-dimethylformamide (DMF), is pre-placed in the kettle. This organic solvent needs to be able to dissolve the raw material well and do not side-react with the raw material and reaction products. < Br > Then, an appropriate amount of catalyst, such as palladium catalyst, such as tetra (triphenylphosphine) palladium, is added in an amount of about 3% to 5% of the amount of raw material. And add bases, such as potassium carbonate, sodium carbonate, etc. The amount of base is preferably to promote the reaction, which is about 1.5 to 2 times the amount of raw material.
Subsequently, the reaction system is heated to a suitable temperature, preferably 60 ° C to 80 ° C. The reaction is stirred at this temperature, and the reaction time is about 6 to 10 hours. During the reaction, the reaction process needs to be closely observed. The method of thin layer chromatography (TLC) can be used to regularly take the reaction liquid for detection. When the raw material point is basically eliminated, the reaction is considered to be basically completed.
After the reaction is completed, the reaction solution is cooled to room temperature, poured into an appropriate amount of water, extracted with an organic solvent, and the organic phase is collected. The organic phase is washed with saturated saline water and dried with anhydrous sodium sulfate. After that, the organic solvent is removed by reduced pressure distillation to obtain a crude product.
The crude product is purified by column chromatography. A silica gel column is selected, and the eluent mixed with petroleum ether and ethyl acetate in a certain proportion is eluted. The fraction containing the target product is collected, and the eluent is removed by rotary evaporation to obtain a pure 2,2 ': 6', 2 '-tripyridine-4' - (4-bromophenyl) product.
2,2 ': 6', 2 '-terpyridine, 4' - (4-bromophenyl) - What is the market price?
I don't know what the market price of "2%2C2%27%3A6%27%2C2%27%27 - terpyridine% 2C 4% 27 - (4 - bromophenyl) -" is. As recorded in "Tiangong Kaiwu", it is mostly agricultural and industrial products, and it may be difficult to involve such fine substances in chemical synthesis. If you want to know its market price today, you need to look for it in today's chemical material market. Or consult chemical raw material merchants, or visit chemical product trading platforms. Today's chemical market, information circulation is quite convenient, search the relevant chemical product websites online, or you can know its approximate price range. Or you can ask experts in the chemical industry, who are familiar with the industry market, or can tell you the price of this substance in detail, but it also depends on quality, purity, supply and demand, etc., to determine the exact price.
2,2 ': 6', 2 '-terpyridine, 4' - (4-bromophenyl) - How stable is it?
2%2C2%27%3A6%27%2C2%27%27 - terpyridine% 2C 4% 27- (4 - bromophenyl) The stability of this substance depends on its chemical structure and the environment in which it is located. In terms of structure, the 2,2 ': 6', 2 '-tripyridine part is connected by three pyridine rings through specific chemical bonds. The pyridine ring itself has certain aromatic stability, and the conjugate system helps to delocalize electrons, reducing the molecular energy and improving the stability.
And the 4' - (4 - bromophenyl) part, the introduction of bromine atoms, although the bromine atom has an electron-sucking induction effect, the conjugation effect of phenyl groups cannot be ignored. Phenyl groups are connected to the tripyridine system to further expand the conjugation range and enhance the overall stability of the molecule. However, the presence of bromine atoms changes the distribution of molecular electron clouds, and under certain reaction conditions, it may become a check point for reactivity.
Due to environmental factors, the temperature increases, the thermal motion of the molecule intensifies, or the vibration of the chemical bond in the molecule increases. When the energy is sufficient to overcome the bond energy, the molecular structure may be damaged and the stability will decrease. In terms of humidity, if the environment is humid, water molecules may interact with the compound, especially when the molecule contains a check point that can form hydrogen bonds with water, or change the intermolecular interaction, affecting its stability.
Furthermore, light is also an important factor. Light energy of a specific wavelength may be absorbed by molecules, triggering electronic transitions, causing chemical reactions to occur, damaging the original structure of molecules and reducing stability. In addition, if there are chemicals that can react with them in the environment, such as strong oxidizing agents, reducing agents, etc., their structure will also be changed due to chemical reactions, affecting stability. Therefore, to maintain the stability of 2%2C2%27%3A6%27%2C2%27%27-terpyridine% 2C 4% 27- (4-bromophenyl), it is necessary to properly control temperature, humidity, light and avoid contact with active chemicals.