2 2 6 2 Terpyridine 4 4 4 Tricarboxylic Acid
pyridine pyrrole pyrazine piperidine piperazine

[2,2':6',2''-terpyridine]-4,4',4''-tricarboxylic acid

    Specifications

    HS Code

    948626

    Chemical Formula C21H13N3O6
    Molar Mass 403.34 g/mol
    Appearance Solid (usually powder)
    Solubility In Water Poor solubility
    Solubility In Organic Solvents Soluble in some polar organic solvents like DMSO
    Melting Point Decomposes rather than having a distinct melting point
    Acidity Carboxylic acid groups make it acidic
    Coordination Ability Good coordination ability to metal ions due to terpyridine moiety
    Color Typically white to off - white
    Crystal Structure Complex, depends on crystallization conditions

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    Frequently Asked Questions

    As a leading [2,2':6',2''-terpyridine]-4,4',4''-tricarboxylic acid supplier, we deliver high-quality products across diverse grades to meet evolving needs, empowering global customers with safe, efficient, and compliant chemical solutions.

    What is the chemical structure of [2,2 ': 6', 2 '-terpyridine] -4, 4', 4 '-tricarboxylic acid
    [2,2 ': 6', 2 '-tripyridine] -4, 4', 4 '-tricarboxylic acid, its chemical structure is quite unique. This compound takes 2,2': 6 ', 2' -tripyridine as the basic skeleton, and is connected with carboxyl groups at its 4,4 ', 4' positions.
    The structural part of tripyridine is connected by three pyridine rings in sequence through specific chemical bonds. The pyridine ring itself has aromatic properties. This polycyclic connection structure endows the molecule with a unique electron cloud distribution and conjugate system. The carboxyl group (-COOH) introduced at the 4,4 ', 4' position not only increases the polarity of the molecule, but also endows it with many special chemical properties. Carboxyl groups are acidic, can participate in acid-base reactions, and can coordinate with metal ions to form various complexes. These complexes have shown broad application prospects in materials science, catalysis and biomedicine.
    The structural characteristics of this compound determine its potential uses in different fields, providing an important structural basis for further research and development of new functional materials.
    [2,2 ': 6', 2 '-terpyridine] -4, 4', 4 '-tricarboxylic acid What are the common synthesis methods
    There are several common methods for the synthesis of [2,2 ': 6', 2 '-tripyridine] -4, 4', 4 '-tricarboxylic acids. One is to use a compound containing a pyridine structure as the starting material, and use an organic synthesis reaction to increase its functional groups. For example, an appropriate pyridine derivative is selected, a halogen atom is added to a specific position in a halogenation reaction, and then a metal-catalyzed coupling reaction is used to connect the pyridine fragments to form a tripyridine structure. Subsequent carboxylation is carried out, and a carboxyl group is introduced at the 4,4', 4 'position of the tripyridine. This process requires fine regulation of reaction conditions, such as temperature, solvent, catalyst dosage, etc., to ensure the selectivity and yield of the reaction.
    Second, the pyridine ring can be gradually constructed from simple raw materials, and then connected to form tripyridine, and finally carboxyl groups are introduced. For example, using aldose, ketone, ammonia, etc. as the starting materials, the pyridine ring is constructed by condensation reaction, and the tripyridine frame is built through multi-step reaction, and then the target product is obtained by suitable carboxylation means. Although this path is complicated, it has high flexibility in raw material selection and reaction design.
    Furthermore, the mature methods reported in the literature can also be used for reference to the synthesis strategies of similar compounds, and the appropriate optimization and adjustment can be made according to the structural characteristics of the target molecule. Such as changing the reaction sequence, selecting a new catalyst or reaction medium, or pretreating the raw materials to improve the reaction efficiency and product purity. These common methods of synthesis have their own advantages and disadvantages, and they need to be carefully selected according to actual needs and conditions.
    [2,2 ': 6', 2 '-terpyridine] -4, 4', 4 '-tricarboxylic acid is used in which fields
    [2,2 ': 6', 2 '-tripyridine] -4, 4', 4 '-tricarboxylic acid, which is useful in various fields. In the field of materials science, it can be used as a ligand for the construction of coordination polymers and metal-organic frameworks. Because it has multiple pyridine nitrogen atoms and carboxyl groups, it can coordinate with metal ions to construct materials with diverse structures and specific properties, which can be used as gas adsorption, separation and catalysis materials.
    In the context of chemical sensing, it can identify specific metal ions. Tripyridine has high selectivity and affinity for certain metal ions. When complexed with metal ions, it may cause changes in the spectral properties of the system, such as changes in fluorescence emission and absorption spectra. This can be used to sensitively detect metal ions, which is of significance for environmental monitoring and biological analysis.
    In the field of biomedicine, it may have potential applications. Because it can form stable complexes with metal ions, it can be designed as a metal-based drug carrier, which can interact with biomolecules to achieve targeted drug delivery. And its good coordination ability may be helpful in the development of biological imaging reagents, which is helpful for early diagnosis of diseases. Due to its unique structure and coordination properties, this compound has shown broad application prospects in materials, sensing, biomedicine and other fields, providing many possibilities for scientific research and technological innovation.
    [2,2 ': 6', 2 '-terpyridine] -4, 4', 4 '-tricarboxylic acid What are the physical and chemical properties
    [2,2 ': 6', 2 '-tripyridine] -4, 4', 4 '-tricarboxylic acid, which is an organic compound containing nitrogen polydentate ligands and carboxyl groups. Its physical and chemical properties are unique, let me tell you one by one.
    In terms of its solubility, it is quite limited in common organic solvents, such as ethanol and dichloromethane. However, in strong polar solvents, such as dimethyl sulfoxide (DMSO), N, N -dimethylformamide (DMF), the solubility is good. Because the carboxyl group is a strong polar group, it can form hydrogen bonds and other interactions with strong polar solvents, thereby enhancing solubility.
    Looking at its stability, it is quite stable under normal conditions. However, in the environment of strong acids and bases, there may be changes. When the carboxyl group encounters a strong acid, it is protonated; when it encounters a strong base, it is deprotonated to form a carboxylate. This structural change may affect its chemical properties and coordination ability.
    Talking about the coordination properties, because it contains multiple nitrogen atoms and carboxyl oxygen atoms, the coordination ability is quite strong. It can form complexes with a variety of metal ions and is widely used in the fields of materials science and catalysis. Nitrogen atoms coordinate with metal ions to form stable coordination bonds; carboxyl oxygen atoms can also participate in coordination, or bridge different metal ions to form complexes with diverse structures.
    In terms of thermal stability, it can be seen from thermogravimetric analysis that the structure is stable within a certain temperature range. When the temperature rises to a specific value, or due to chemical bond breaking or decomposition, the mass gradually decreases. The specific thermal decomposition temperature varies depending on the purity of the sample and the test conditions.
    [2,2 ': 6', 2 '-tripyridine] 4,4', 4 '-tricarboxylic acid has unique physical and chemical properties and shows potential application value in many fields. It is a compound worthy of further investigation.
    [2,2 ': 6', 2 '-terpyridine] -4, 4', 4 '-tricarboxylic acid What is the market outlook?
    [2,2 ': 6', 2 '-tripyridine] -4,4', 4 '-tricarboxylic acid, this compound is crucial in the field of material chemistry and coordination chemistry, and is widely used in the construction of metal-organic frameworks (MOFs) and the design of new ligands. Due to its unique coordination mode and good electronic properties, it can efficiently coordinate with many metal ions to form complexes with diverse structures and unique properties.
    Looking at its market prospects, in recent years, with the surge in demand for functional materials in scientific research, the attention of this compound has continued to rise. In the field of academic research, many research teams have dedicated themselves to the synthesis and performance exploration of metal complexes with them as ligands for cutting-edge research such as gas adsorption, catalysis, and fluorescence sensing, which has undoubtedly promoted the growth of the compound's demand in the scientific reagent market.
    In the industrial field, with the exploration of high-performance materials, MOFs materials constructed based on this compound have shown potential application value in separation, catalysis, etc. Some chemical companies and materials R & D institutions have started relevant application research and technology development, indicating that the demand for them in industrial production may increase significantly in the future.
    However, its market development also faces challenges. The complexity and high cost of the synthesis process limit large-scale production and wide application. In order to expand the market, it is urgent to develop more efficient and economical synthesis methods. But overall, in view of the strong demand for new functional materials in scientific research and industry, the market prospect of [2,2 ': 6', 2 '-tripyridine] -4,4', 4 '-tricarboxylic acid is broad. If the synthesis problem is solved in time, it is expected to shine in the field of materials and achieve wider application and promotion.